Personally, I wouldn't say that it's worth changing from a DSPZ7 to an SCLX83. They're both excellent, and roughly on par with each other, give or take a couple of things.
I moved from a Yamaha 3800 to a Pioneer 82, and found the Pioneer drove and controlled my old M&K S150's much better than the Yamaha did. It was quite a difference, so much so, I changed to the 83 when that was released. The DSPZ7 wasn't quite good enough to drive S150's properly, and couldn't make them sound how they were intended to. It was much better suited to the M&K LCR750's (a model below the S150's). The DSPZ7/LCR750 combo was perfect.
So if you find your Missions are demanding more than your Z7 can give, it's worth trying the Pioneers, as they have more grip due to their digital amplification. If you feel the Z7 runs them fine, then your next step is really going to be the pre/power route in order to improve things - something like the Onkyo 5509 with a good multi-channel power amp. The 5509 will give you better processing and much better room EQ, as well as independent ISF settings for each video input. Or, you could add a better power amp to your DSPZ7 and use it as a processor.
Think carefully - you have a great receiver!