I'm afraid I can't give you a definite answer. But I remember reading somewhere that both outputs couldn't be used at the same time—although they didn't explain why, and I can't remember where.
The design is not internally balanced, but the balanced signal is generated at the output stage. That means that the RCA and XLR connections quite probably, and logically, share the op-amps or whatever there is at the output stage. But really, I don't have a clue.
Anyways, John Westlake who is one of the two people who designed the 8200CDQ, among other stuff for Audiolab and other vendors, is quite active at the PFM forum. He's been known to provide good insight about the products he has designed—even when support from Audiolab failed. I'd check the manual, contact Audiolab, and if everything else, try reaching out to JohnW there.