No that is missing the point.
PCM requires no decoding; therefore PCM soundtracks are read off the disc and are subject to the minimum processing right throughout the chain. For example Casino Royale boasts a 5.1 uncompressed PCM soundtrack and no DOLBY True HD or DTS Master Audio, both of which can be decoded either by a player or an amp which turns the soundtrack into PCM channels.
Therefore opting for the PCM soundtrack will not depend on what the receiver or the amp can decode.