Rob,
Running rear mono-pole speakers out of phase will do noting but ruin your rear sound stage. Dipole speakers operate in a specific manner, with two drivers, one running out of phase and one running in phase, on opposing sides of the speaker.
The whole purpose of this arrangement is to create a null area directly in front of the speaker (a null being an area where very little sound can be heard from the speaker). The reason for doing this is so that the speaker can be placed fairly close to the listener whilst reducing the localisation of that speaker that the listener would otherwise experience if it was direct firing. This then tricks the listener into thinking the sounds are further away, and the sound field therefore appears more diffuse.
Setting your speakers out of phase won't achieve this, they'll just sound 'phasey' with a collapsed stereo sound stage.
Personally I don't like dipoles, I think their performance is compromised by design. Bi-poles are much better (fortunately many di-pole speakers have a switch that also allows bi-pole operation). Here both drivers run in phase, so no null is created, but you still get a broad dispersion that creates a more diffuse sound field and less localisation.
If you are using mono-pole speakers for your rears, and are experiencing too much localisation, you'd be far better to try angling them away from the MLP, or raising them higher than the MPL (surround should ideally be at least 1ft above ear level in most cases anyway).
- Gareth